445-27-2
- Product Name：2'-Fluoroacetophenone
- Molecular Formula：C8H7FO
- Purity：99%
- Molecular Weight：138.141
Product Details;
CasNo： 445-27-2
Molecular Formula： C8H7FO
Appearance： Clear colorless to light yellow or light green
Wholesale! Buy Reliable Quality 2'-Fluoroacetophenone 445-27-2 In Stock
- Molecular Formula:C8H7FO
- Molecular Weight:138.141
- Appearance/Colour:Clear colorless to light yellow or light green
- Melting Point:26-27 °C
- Refractive Index:n20/D 1.507(lit.)
- Boiling Point:180.8 °C at 760 mmHg
- Flash Point:67.5 °C
- PSA：17.07000
- Density:1.103 g/cm3
- LogP:2.02830
445-27-2 Relevant articles
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445-27-2 Process route
-
- 445-26-1
1-(2-fluorophenyl)ethanol
-
- 445-27-2
2'-Fluoroacetophenone
Conditions
| Conditions | Yield |
|---|---|
|
With [(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine)RuCl2(PPh3)]; potassium tert-butylate; acetone; In methanol; at 56 ℃; for 0.5h; under 750.075 Torr; Catalytic behavior; Inert atmosphere;
|
97% |
|
With Langlois reagent; In acetonitrile; at 25 ℃; for 12h; Irradiation; Sealed tube;
|
89% |
|
With calcomenite; potassium hydroxide; In toluene; for 28h; Reflux;
|
87% |
|
With caesium carbonate; In toluene; at 110 ℃; for 18h;
|
77% |
|
With tert.-butylhydroperoxide; In water; at 100 ℃; for 24h;
|
72% |
|
With potassium tetrakis-μ-pyrophosphitodiplatinate(II); In water; at 20 ℃; for 8h; Inert atmosphere; Irradiation;
|
55% |
|
With pyridinium chlorochromate; In dichloromethane;
|
|
|
With sodium hypochlorite; N-Bromosuccinimide; [(R,R)-(N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminato)]manganese(III) chloride; In dichloromethane; water; at 25 ℃; for 0.17h; chemoselective reaction;
|
|
|
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; Trametes versicolor laccase; In tert-butyl methyl ether; at 30 ℃; for 16h; pH=5; Solvent; Reagent/catalyst; Catalytic behavior; Enzymatic reaction;
|
|
|
With [fac-N-(2-(diphenylphosphino)ethyl)-5,6,7,8-tetrahydroquinolin-8-amine]RuCl2(triphenylphosphine); potassium tert-butylate; In para-xylene; for 24h; Catalytic behavior; Reflux; Inert atmosphere;
|
|
|
With oxygen; at 120 ℃; for 12h;
|
|
|
With C44H52N2O4Ru; 4-methylmorpholine N-oxide; In acetonitrile; at 82 ℃; for 1h; Inert atmosphere;
|
87 %Chromat. |
|
With dipropylene glycol dimethyl ether; oxygen; at 120 ℃;
|
-
- 1993-03-9
o-fluorophenylboronic acid
-
- 75-05-8,26809-02-9
acetonitrile
-
- 445-27-2
2'-Fluoroacetophenone
Conditions
| Conditions | Yield |
|---|---|
|
With 1,10-Phenanthroline; nickel(II) bromide diethylene glycol dimethyl ether; sodium hydrogencarbonate; In water; at 100 ℃; for 5h; Autoclave;
|
89% |
445-27-2 Upstream products
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445-27-2 Downstream products
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389-42-4
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70243-84-4
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-
39911-06-3
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-
117677-94-8
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