82-34-8
- Product Name：1-Nitroanthraquinone
- Molecular Formula：C14H7 N O4
- Purity：99%
- Molecular Weight：253.214
Product Details;
CasNo： 82-34-8
Molecular Formula： C14H7 N O4
Hot Sale Factory Supply High Purity 1-Nitroanthraquinone 82-34-8 In Bulk Supply
- Molecular Formula:C14H7 N O4
- Molecular Weight:253.214
- Vapor Pressure:4.51E-09mmHg at 25°C
- Melting Point:232.5~233.5℃
- Refractive Index:1.4700 (estimate)
- Boiling Point:471.8 °C at 760 mmHg
- Flash Point:243.3 °C
- PSA：79.96000
- Density:1.481 g/cm3
- LogP:2.89340
1-NITROANTHRAQUINONE(Cas 82-34-8) Usage
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Chemical Properties |
Yellow needles from AcOH;yellow plates by sublimation; soluble in EtOH and Et2O; slightly soluble in EtOAc, benzene and CHCl3; insoluble in water. |
| Uses | 1-NITROANTHRAQUINONE is a very important reagent in the manufacture of a wide range of dyestuffs, pharmaceuticals, and the like, being used either as such, or after reduction to l-aminoanthraquinone. |
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Synthesis Reference(s) |
Tetrahedron Letters, 16, p. 1429, 1975 DOI: 10.1016/S0040-4039(00)72160-5 |
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Hazard |
Hepatotoxic; moderately toxic; may cause hepatocellular neoplasms, subcutaneous fibromas, subcutaneous hemangiosarcomas, and type II pneumocyte proliferation. |
InChI:InChI=1/C14H7NO4/c16-13-8-4-1-2-5-9(8)14(17)12-10(13)6-3-7-11(12)15(18)19/h1-7H
82-34-8 Relevant articles
Photoinduced electron transfer from excited [tris(2,2'- bipyridine)ruthenium(II)]2+ to a series of anthraquinones with small positive or negative Gibbs energy of reaction. Marcus behavior and negative activation enthalpies
Frank, Rudolf,Greiner, Gerhard,Rau, Hermann
, p. 3481 - 3490 (1999)
In the electron transfer (ET) quenching ...
An Efficient Procedure for the Preparation of 1-Nitroanthraquinone
Hashem Sharghi &Fatemeh Tamaddon
, An International Journal for Rapid Communication of Synthetic Organic Chemistry Volume 21, 1991 - Issue 22
A novel and efficient method is developed for the selective mono nitration of anthraquinone (1). A mixture of fuming nitric acid, sulfuric acid and phosphoric acid in carbon tetrachloride is introduced as a new nitrating system for the high yield preparation of 1-nitroanthraquinone.
The invention relates to a pyrrolidone ionic liquid as catalyst preparation 1 - nitroanthraquinone method
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Paragraph 0028; 0029; 0030; 0031; 0032; 0033; 0034-0040, (2018/03/26)
The invention belongs to the technical f...
82-34-8 Process route
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- 84-65-1
9,10-phenanthrenequinone
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- 82-34-8
1-nitroanthraquinone
| Conditions | Yield |
|---|---|
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In water; nitric acid;
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99.2% |
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With phosphoric acid; sulfuric acid; nitric acid; In tetrachloromethane; for 6h; Ambient temperature;
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90% |
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With nitric acid; In water;
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71% |
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71% |
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With nitric acid;
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71% |
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With nitric acid; In water;
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69% |
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With nitric acid; In water;
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67.1% |
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With nitric acid;
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66% |
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With nitric acid;
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63% |
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With nitric acid; at -5 - 0 ℃; for 1h;
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53% |
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With nitric acid;
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With sulfuric acid; nitric acid; at 100 ℃;
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With sulfuric acid; nitric acid; at 50 ℃;
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With nitric acid; at 55 - 75 ℃;
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With sulfuric acid; nitric acid;
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With nitric acid; In sulfuric acid;
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With hydrogen fluoride; nitric acid; In water;
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With nitric acid; In hydrogen fluoride; water;
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With nitric acid; In hydrogen fluoride;
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With nitric acid;
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With nitric acid;
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With nitric acid; In water;
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With nitric acid; In paraffin oil;
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With nitrogen dioxide; ozone; In 1,2-dichloro-ethane; at 20 - 22 ℃; for 8h; Reagent/catalyst; Temperature; Solvent;
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With fuming sulphuric acid; nitric acid; toluene-4-sulfonic acid; In 1,2-dichloro-ethane; N,N-dimethyl-formamide; at 30 - 40 ℃; for 16h; Solvent;
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-
- 7335-77-5
6-nitro-o-benzoylbenzoic acid
-
- 82-34-8
1-nitroanthraquinone
| Conditions | Yield |
|---|---|
|
With sodium carbonate; In sulfuric acid; water;
|
85% |
82-34-8 Upstream products
-
120-12-7
anthracene
-
82-49-5
1-anthraquinonesulfonic acid
-
54401-95-5
1-nitroso-anthraquinone
-
2159-38-8
2-(3'-nitrobenzoyl)benzoic acid
82-34-8 Downstream products
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4946-83-2
1-piperidinoanthraquinone
-
345265-55-6
1-(piperazin-1-yl)-9,10-anthraquinone
-
129-43-1
1-hydroxyanthraquinone
-
5960-64-5
1-(benzylamino)-9,10-anthraquinone
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